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PCL Polyols

Chemical Structure: Polycaprolactone-based polyols with repeating caprolactone units

Physical State: Typically viscous liquids or semi - solids

Hydroxyl Number: Varies depending on molecular weight and functionality, usually in the range of 10 - 500 mg KOH/g

Molecular Weight: Can range from a few hundred to several thousand g/mol

Functionality: Typically 2 - 6 hydroxyl groups per molecule

Viscosity: Higher viscosities compared to some other polyols, influenced by molecular weight

Solubility: Soluble in many organic solvents like acetone, toluene

Thermal Stability: Good thermal stability up to a certain temperature, decomposes at high temperatures

Tg (glass Transition Temperature): Relatively low, depending on molecular structure

Reactivity: High reactivity with isocyanates for polyurethane synthesis

FAQ

What are the main applications of PCL polyols?

PCL polyols, or polycaprolactone polyols, have several main applications.PCL polyols or polycaprolactones have several main applications.
One significant application is in the field of coatings.Coatings is a significant application. PCL polyols are used to formulate high - performance coatings.PCL polyols can be used to formulate high-performance coatings. Their low - viscosity nature allows for easy processing and application, whether by spraying, brushing, or dipping.Their low-viscosity allows for easy processing and applications, whether by brushing, spraying, or dipping. These polyols can enhance the hardness, abrasion resistance, and chemical resistance of the coatings.These polyols increase the coatings' hardness, chemical resistance, and abrasion resistance. For example, in automotive coatings, they contribute to the durability of the finish, protecting the vehicle from scratches and environmental factors like UV radiation and moisture.In automotive coatings, for example, they can increase the durability of the finish and protect the vehicle against environmental factors such as UV radiation and moisture. In industrial coatings, they help maintain the integrity of the coated surfaces in harsh operating conditions.In industrial coatings they help maintain the integrity and durability of the coated surfaces under harsh operating conditions.

PCL polyols are also widely used in the production of adhesives.PCL polyols can also be used to make adhesives. They offer excellent adhesion properties to a variety of substrates, including metals, plastics, and ceramics.They have excellent adhesion to a wide range of substrates including metals and plastics. Their flexibility and low - temperature performance make them suitable for applications where the adhesive needs to withstand temperature fluctuations.They are suitable for applications that require an adhesive to be flexible and low-temperature. In the packaging industry, PCL - based adhesives are used to bond different materials together, ensuring the stability of the packages.In the packaging industry PCL-based adhesives are used for bonding different materials together to ensure the stability of packages. They can also be found in the assembly of electronic devices, where they provide reliable adhesion without causing damage to sensitive components.These adhesives are also used in the assembly of electronic products, where they provide reliable adherent without damaging sensitive components.

In the area of elastomers, PCL polyols play a crucial role.PCL polyols are important in the field of elastomers. By reacting with diisocyanates, they can form polyurethane elastomers.They can be converted into polyurethane by reacting with diisocyanates. These elastomers have a unique combination of properties such as high elasticity, good mechanical strength, and resistance to oils and solvents.These elastomers combine a variety of properties, including high elasticity, mechanical strength and resistance to oil and solvents. They are used in applications like seals, gaskets, and shock - absorbing components.They are used for applications such as seals, gaskets and shock-absorbing components. For instance, in the automotive suspension systems, the elastomers made from PCL polyols can effectively absorb vibrations and shocks, improving the ride comfort and the lifespan of the vehicle components.In the automotive suspension system, for example, the elastomers produced from PCL polyols are able to absorb vibrations and reduce shocks, thereby improving ride comfort and the life of the vehicle components.

Another important application is in the biomedical field.Biomedical applications are also important. PCL polyols are biocompatible and biodegradable, making them suitable for drug delivery systems.PCL polyols can be used as drug delivery systems because they are biocompatible and degradable. They can be formulated into microspheres or nanoparticles that encapsulate drugs.They can be formulated as microspheres or Nanoparticles to encapsulate drugs. The slow degradation of PCL in the body allows for a controlled release of the drug over an extended period, improving the efficacy and reducing the frequency of dosing.The slow degradation of PCL allows for a controlled drug release over a longer period of time, improving efficacy and reducing dosage frequency. Additionally, PCL - based polymers can be used in tissue engineering scaffolds.PCL-based polymers are also useful in tissue engineering scaffolds. Their mechanical properties and ability to support cell adhesion and proliferation make them ideal for creating structures that can guide tissue regeneration.Their mechanical properties, as well as their ability to support cell proliferation and adhesion, make them ideal for creating scaffolds that can guide tissue regeneration.

What are the advantages of PCL polyols compared to other materials?

PCL polyols, or polycaprolactone polyols, offer several advantages when compared to other materials.PCL polyols or polycaprolactones offer a number of advantages over other materials.
One key advantage is their excellent hydrolytic stability.Their excellent hydrolytic stability is a key advantage. PCL polyols degrade slowly under normal environmental conditions.PCL polyols are slowly degraded in normal environmental conditions. This is in contrast to some other polyols that can break down rapidly when exposed to moisture.This is in contrast with some other polyols which can degrade rapidly when exposed moisture. For example, certain polyester polyols made from more hydrophilic monomers may be more prone to hydrolysis.Some polyester polyols, for example, made from monomers that are more hydrophilic may be more susceptible to hydrolysis. The slow degradation of PCL polyols makes them suitable for applications where long - term stability is crucial, such as in coatings and adhesives that need to withstand varying humidity levels over extended periods.PCL polyols are suited for applications that require long-term stability, such as coatings and adhesives.

PCL polyols also have a relatively low melting point.PCL polyols have a low melting point. This property allows for easier processing.This property makes processing easier. In manufacturing processes like extrusion or injection molding, the low melting point enables the material to flow more readily into molds or through extruder dies.The low melting point allows the material to flow easier through extruder dies or into molds in manufacturing processes such as extrusion and injection molding. Compared to materials with high melting points, less energy is required to process PCL polyols, which can lead to cost savings in production.PCL polyols can be processed with less energy than materials with higher melting points. This can result in cost savings. Additionally, the low melting point can contribute to better adhesion to substrates, as the molten PCL polyol can more effectively wet the surface during application.The low melting point of PCL polyols can also contribute to better adhesion, as the PCL polyol molten can wet the substrate more effectively during application.

Another advantage lies in their solubility characteristics.Their solubility is another advantage. PCL polyols are soluble in a wide range of organic solvents.PCL polyols can be dissolved in a variety of organic solvents. This solubility provides flexibility in formulating products.This flexibility is provided by the solubility. For instance, in the preparation of liquid - based coatings or inks, the ability to dissolve the polyol in different solvents allows formulators to adjust the viscosity, drying time, and other properties of the final product.In the preparation of liquid-based coatings or dyes, for example, the formulators can adjust the viscosity and drying time of the final product by dissolving the polyol with different solvents. In contrast, some other polyols may have limited solubility, restricting the choice of solvents and potentially limiting the performance of the formulated product.Some polyols, however, may be limited in their solubility. This can limit the choice of solvents, and therefore the performance of a formulated product.

PCL polyols are biocompatible.PCL polyols have a biocompatible nature. This makes them highly valuable in biomedical applications.They are therefore highly useful in biomedical applications. When used in drug delivery systems or tissue engineering scaffolds, they do not cause significant adverse reactions in the body.They do not cause any adverse reactions when used as scaffolds or drug delivery systems. Many other synthetic materials may be rejected by the body's immune system or cause inflammation.Other synthetic materials can be rejected by the immune system or cause inflammation. The biocompatibility of PCL polyols opens up opportunities for use in implants, where they can gradually degrade over time as the body heals, without leaving behind harmful residues.The biocompatibility and biodegradability of PCL polyols makes them suitable for use in implants. They can gradually degrade as the body heals without leaving harmful residues.

Finally, PCL polyols can be tailored to have different molecular weights and functionality.PCL polyols are also available in a variety of molecular weights, allowing them to be tailored for specific functionality. By controlling the polymerization process, manufacturers can produce PCL polyols with specific properties.Manufacturers can produce PCL Polyols that have specific properties by controlling the polymerization. For example, a higher molecular weight PCL polyol may be used to enhance the mechanical strength of a polymer blend, while a lower molecular weight one can be used to improve the flexibility.A PCL polyol with a higher molecular mass can be used to increase the mechanical strength of the polymer blend while a PCL polyol with a lower weight can be used for increased flexibility. This adjustability gives PCL polyols an edge over materials with more fixed properties, allowing for customization to meet the specific requirements of various applications.PCL polyols are more flexible than materials with fixed properties and can be customized to meet the needs of different applications.

How is the quality of PCL polyols determined?

The quality of PCL polyols can be determined through several aspects.The quality of PCL Polyols is determined by several factors.
First, the molecular weight and its distribution play a crucial role.First, the molecular mass and its distribution are crucial. The molecular weight of PCL polyols affects the physical and chemical properties of the final products.The molecular mass of PCL polyols influences the physical and chemistry properties of the end products. High - molecular - weight PCL polyols may result in products with higher viscosity and mechanical strength.High-molecular-weight PCL polyols can result in products that are viscous and have a higher mechanical strength. Gel permeation chromatography (GPC) is a common method to accurately measure the molecular weight and its distribution.Gel permeation (GPC), a method widely used to measure molecular weight, is an accurate way to determine the distribution of the molecular mass. By comparing the measured values with the expected or specified molecular weight range, one can assess the quality in terms of molecular - weight - related characteristics.Comparing the measured values to the expected or specified range of molecular weights, one can assess quality in terms molecular-weight-related characteristics. If the molecular - weight distribution is too broad, it may lead to inconsistent performance in applications.If the molecular-weight distribution is too wide, it can lead to inconsistent performance.

Second, the hydroxyl value is an important indicator.Second, the hydroxyl number is a very important indicator. The hydroxyl value reflects the number of hydroxyl groups per unit mass of the PCL polyol.The hydroxyl value is the number of hydroxyl group per unit mass of PCL polyol. It is directly related to the reactivity of the polyol in reactions, especially in the synthesis of polyurethanes and other polymers.It is directly correlated with the polyol's reactivity in reactions, particularly in the synthesis and polyurethanes. Titration methods are typically used to determine the hydroxyl value.To determine the hydroxyl values, titration methods are usually used. A precise hydroxyl value measurement ensures that the PCL polyol can react as expected in subsequent chemical reactions.A precise measurement of the hydroxyl value ensures that PCL polyol will react as expected during subsequent chemical reactions. Deviations from the desired hydroxyl value can cause issues such as incomplete reactions, incorrect stoichiometry, and ultimately, poor - quality final products.Deviations from the desired value of hydroxyl can lead to incomplete reactions, incorrect stoichiometry and, ultimately, poor-quality final products.

Third, the acid value should be considered.Third, it is important to consider the acid value. The acid value indicates the amount of acidic impurities in the PCL polyol.The acid value is a measure of the amount acidic impurities present in the PCL polyol. High acid values can have a negative impact on the stability of the polyol during storage and its reactivity in chemical reactions.High acid values may have a negative effect on the stability and reactivity of the polyol in chemical reactions. Acid - catalyzed side - reactions may occur if the acid value is too high.If the acid value is high, it can cause acid-catalyzed reactions. Titration with a base can be used to measure the acid value.Acid value can be measured by titration with a basic. A low and consistent acid value is desirable for high - quality PCL polyols.For high-quality PCL polyols, a low and consistent pH value is desired.

Fourth, the moisture content needs to be monitored.Fourth, moisture content should be monitored. Moisture in PCL polyols can interfere with chemical reactions, especially those sensitive to water, like the formation of polyurethanes.Moisture can interfere with certain chemical reactions, such as the formation of polyurethanes, which are sensitive to water. Moisture can react with isocyanates in polyurethane synthesis, leading to the formation of urea linkages and foaming, which can ruin the product quality.Moisture in PCL polyols can interfere with chemical reactions, especially those sensitive to water, like the formation of polyurethanes. Karl Fischer titration is a common method to measure the moisture content accurately.Karl Fischer titration can be used to accurately measure moisture content. Keeping the moisture content within a specified low limit is essential for maintaining the quality of PCL polyols.Maintaining the PCL polyols' quality requires that the moisture content be kept within a low limit.

Finally, the appearance and color of PCL polyols can also provide some insights into their quality.The color and appearance of PCL polyols also provides some insight into their quality. A clear and color - less or slightly - colored product usually indicates fewer impurities.A product that is clear and has a color - a little or hardly - indicates less impurities. Cloudiness or a significant change in color may suggest the presence of contaminants, oxidation, or improper manufacturing processes.Cloudiness or a significant color change may indicate the presence of contaminants, improper manufacturing processes, or oxidation. Visual inspection can be a simple yet effective first - step in assessing the quality of PCL polyols.Visual inspection is a simple but effective way to assess the quality of PCL Polyols.

What are the storage and handling requirements for PCL polyols?

PCL polyols, or polycaprolactone polyols, have specific storage and handling requirements to maintain their quality and performance.PCL polyols (or polycaprolactones) have specific storage and handling needs to maintain their performance and quality.
Storage requirements:Storage requirements

1. Temperature control: PCL polyols should be stored in a cool and dry environment.Temperature control PCL polyols must be stored in a dry and cool environment. The recommended storage temperature typically ranges from 5 to 35 degrees Celsius.The recommended temperature ranges between 5 and 35 degrees Celsius. Temperatures outside this range can affect the physical properties of the polyol.Temperatures outside of this range can affect physical properties of polyol. High temperatures may lead to increased viscosity and potential degradation over time, while extremely low temperatures can cause the polyol to solidify.High temperatures can lead to an increase in viscosity, and over time, degradation. Extremely low temperatures can cause polyol to harden. If it solidifies, proper warming procedures must be followed to return it to a usable state without causing damage.If it solidifies, it must be re-heated to a usable condition without causing any damage.
2. Moisture protection: PCL polyols are sensitive to moisture.PCL polyols can be sensitive to moisture. Exposure to moisture can initiate hydrolysis reactions, which can change the molecular weight and functionality of the polyol.Moisture exposure can cause hydrolysis reactions that can alter the molecular weight of the polyol and its functionality. This can ultimately impact the performance of the final products in which it is used, such as polyurethanes.This can have a negative impact on the performance of final products, such as polyurethanes. To prevent moisture ingress, the polyol should be stored in tightly sealed containers.To prevent moisture from entering the polyol, it should be stored in tightly-sealed containers. Containers should be kept in a dry area, away from sources of humidity like open water or areas prone to condensation.Containers should be stored in a dry place, away from sources like open water and areas prone condensation.
3. Storage containers: Suitable storage containers for PCL polyols are those made of materials that are compatible with the polyol.Storage containers: Containers that are compatible with PCL polyols should be used for storage. Stainless - steel or high - density polyethylene containers are commonly used.Containers made of stainless steel or high-density polyethylene are most commonly used. These materials do not react with the polyol and help maintain its integrity.These materials are non-reactive and help to maintain the integrity of the polyol. Additionally, the containers should be clean and free from any contaminants that could potentially affect the polyol's quality.The containers should also be clean and free of any contaminants that may affect the polyol’s quality.

Handling requirements:

1. Ventilation: When handling PCL polyols, ensure adequate ventilation in the work area.Ventilation is important when handling PCL polyols. Although PCL polyols are generally considered to have low toxicity, good ventilation helps to prevent the build - up of any potential fumes or vapors that may be present during handling.While PCL polyols tend to be low-toxic, good ventilation can help prevent the build-up of fumes and vapors during handling. This is especially important during operations such as pouring, mixing, or heating the polyol.This is particularly important when pouring, heating, or mixing the polyol.
2. Mixing and blending: If PCL polyols need to be mixed with other substances, it is crucial to use appropriate mixing equipment.Mixing and blending is important if PCL polyols are to be mixed with another substance. Gentle agitation is often sufficient to ensure uniform distribution.It is not necessary to use vigorous agitation in order to achieve uniform distribution. Over - mixing or using high - shear mixing for extended periods may cause unwanted degradation or changes in the polyol's properties.Over-mixing or using high-shear mixing for prolonged periods can cause undesirable degradation or changes to the polyol’s properties.
3. Personal protective equipment (PPE): Workers handling PCL polyols should wear appropriate PPE.Personal protective equipment: Workers handling polyols PCL should wear the appropriate PPE. This may include safety glasses to protect the eyes from splashes, gloves to prevent skin contact, and in some cases, a lab coat or protective clothing to avoid soiling of regular clothes.Safety glasses can protect the eyes against splashes. Gloves can prevent skin contact. In some cases, protective clothing or a lab coat may be required to avoid soiling regular clothes. In case of contact with skin or eyes, immediate rinsing with plenty of water is recommended, and medical attention should be sought if necessary.If the product comes into contact with your skin or eyes, you should immediately rinse with water and seek medical attention if needed.

What is the price range of PCL polyols?

The price range of PCL polyols can vary significantly based on several factors.PCL polyols are available at a wide range of prices depending on a number of factors.
One of the key determinants is the production scale.The scale of production is a key factor. Larger - scale production often benefits from economies of scale, which can lead to a lower per - unit cost.Economies of scale can often be achieved by larger-scale production, resulting in a lower cost per unit. Manufacturers that produce PCL polyols in bulk can spread out fixed costs such as equipment investment, research and development, and overheads over a larger volume of product, potentially reducing the price.Producers of PCL polyols can spread fixed costs, such as equipment investments, research and development and overheads, over a greater volume of product. This could lead to a lower price.

The purity and quality of PCL polyols also play a crucial role.Purity and quality of PCL Polyols are also important. High - purity PCL polyols with strict quality control measures, having fewer impurities and consistent molecular weight distributions, typically command a higher price.PCL polyols that are high-purity, have strict quality control, and have consistent molecular weight distributions command a higher cost. These high - quality products are often demanded by industries where precision and reliability are of utmost importance, such as in the production of high - end coatings, adhesives, and biomedical materials.These high-quality products are frequently demanded by industries that place a high value on precision and reliability, such as the production of high-end coatings, adhesives and biomedical material.

Another factor influencing the price is the raw materials used in the production of PCL polyols.The raw materials used to produce PCL polyols also influence the price. The cost of starting materials like e - caprolactone can fluctuate depending on factors such as global supply and demand, geopolitical situations, and changes in the cost of petrochemical feedstocks.The price of raw materials such as e – caprolactone may fluctuate due to factors like global supply and demand. Geopolitical conditions and changes in petrochemical feedstocks can also affect the cost. If the price of e - caprolactone increases, it is likely to be reflected in the price of PCL polyols.PCL polyols will likely increase in price if the price of e-caprolactone increases.

In general, the price of PCL polyols can range from around $5 to $30 per kilogram.PCL polyols are generally priced between $5 and $30 per kilogram. Lower - end PCL polyols, perhaps with relatively lower purity or produced on a smaller scale for less demanding applications like some basic polyurethane formulations, may be at the lower end of this range, closer to $5 - $10 per kilogram.PCL polyols at the lower end, with a lower purity, or produced in smaller quantities for less demanding applications, such as some basic polyurethane formulas, could be closer to $5-$10 per kilogram. On the other hand, high - purity, specialty - grade PCL polyols for applications like medical device manufacturing or advanced electronics coatings can cost upwards of $20 - $30 per kilogram.Specialty - grade PCL Polyols, such as those used in medical device manufacturing and advanced electronics coatings, can cost up to $20 - 30 per kilogram. However, it's important to note that these are approximate price ranges, and actual prices can change over time due to market dynamics, technological advancements in production, and shifts in regulatory requirements.It's important to remember that these are only approximate price ranges. Prices can change over time as a result of market dynamics, technological advances in production and changes in regulatory requirements.

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